The accident happened around 7.20 pm near Bahanaga Bazar station when the train was on the way to Chennai Central station from Shalimar station near Kolkata, they said.
Odisha's Special Relief Commissioner Satyabrata Sahoo said 47 people have so far been admitted to the Balasore Medical College and Hospital.
A PTI reporter at the spot said several people were trapped under the derailed coaches, and locals were assisting emergency services personnel to rescue them, but darkness was hindering the operation.
Chief Minister Naveen Patnaik directed Sahoo and Revenue Minister Pramila Malik to rush to the accident site, officials said.
Accident relief trains have been dispatched to the spot, a South Eastern Railway official said.
Four units of the Odisha Disaster Rapid Action Force (ODRAF), three units of NDRF and 60 ambulances were working to rescue the injured, officials said.
The Odisha government has issued helpline number 06782-262286. The railway helplines are 033-26382217 (Howrah), 8972073925 (Kharagpur), 8249591559 (Balasore) and 044- 25330952 (Chennai).
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